"The greenhouse effect works like this: Energy arrives from the sun in the form of visible light and ultraviolet radiation. The Earth then emits some of this energy as infrared radiation. Greenhouse gases in the atmosphere 'capture' some of this heat, then re-emit it in all directions - including back to the Earth's surface.
Through this process, CO2 and other greenhouse gases keep the Earth’s surface 33°Celsius (59.4°F) warmer than it would be without them. We have added 42% more CO2, and temperatures have gone up. There should be some evidence that links CO2 to the temperature rise.
So far, the average global temperature has gone up by about 0.8 degrees C (1.4°F):
"According to an ongoing temperature analysis conducted by scientists at NASA’s Goddard Institute for Space Studies (GISS)…the average global temperature on Earth has increased by about 0.8°Celsius (1.4°Fahrenheit) since 1880. Two-thirds of the warming has occurred since 1975, at a rate of roughly 0.15-0.20°C per decade."
The temperatures are going up, just like the theory predicted. But where’s the connection with CO2, or other greenhouse gases like methane, ozone or nitrous oxide?
The connection can be found in the spectrum of greenhouse radiation. Using high-resolution FTIR spectroscopy, we can measure the exact wavelengths of long-wave (infrared) radiation reaching the ground.
Figure 1: Spectrum of the greenhouse radiation measured at the surface. Greenhouse effect from water vapour is filtered out, showing the contributions of other greenhouse gases (Evans 2006).
Sure enough, we can see that CO2 is adding considerable warming, along with ozone (O3) and methane (CH4). This is called surface radiative forcing, and the measurements are part of the empirical evidence that CO2 is causing the warming.
How long has CO2 been contributing to increased warming? According to NASA,“Two-thirds of the warming has occurred since 1975”. Is there a reliable way to identify CO2’s influence on temperatures over that period?
There is: we can measure the wavelengths of long-wave radiation leaving the Earth (upward radiation). Satellites have recorded the Earth's outbound radiation. We can examine the spectrum of upward long-wave radiation in 1970 and 1997 to see if there are changes.
Figure 2: Change in spectrum from 1970 to 1996 due to trace gases.'Brightness temperature' indicates equivalent blackbody temperature (Harries 2001).
This time, we see that during the period when temperatures increased the most, emissions of upward radiation have decreased through radiative trapping at exactly the same wavenumbers as they increased for downward radiation. The same greenhouse gases are identified: CO2, methane, ozone etc.
The Empirical Evidence
As temperatures started to rise, scientists became more and more interested in the cause. Many theories were proposed. All save one have fallen by the wayside, discarded for lack of evidence. One theory alone has stood the test of time, strengthened by experiments.
We know CO2 absorbs and re-emits longwave radiation (Tyndall). The theory of greenhouse gases predicts that if we increase the proportion of greenhouse gases, more warming will occur (Arrhenius).
Scientists have measured the influence of CO2 on both incoming solar energy and outgoing long-wave radiation. Less longwave radiation is escaping to space at the specific wavelengths of greenhouse gases. Increased longwave radiation is measured at the surface of the Earth at the same wavelengths.
These data provide empirical evidence for the predicted effect of CO2." http://www.theconsensusproject.com/empirical-...